Broccoli seed oil: SAP value and fatty acids

Broccoli seed oil has a saponification value of 178 mg KOH/g. One gram needs 0.127 g of sodium hydroxide (NaOH) for bar soap or 0.178 g of potassium hydroxide (KOH) for liquid soap to turn fully into soap, before any superfat.

Key numbers

SAP, NaOH
0.126893 g per g oil
SAP, KOH
0.178 g per g oil
Saponification value
178 mg KOH/g
INCI name
Brassica Oleracea Italica Seed Oil

Example: 100 g of Broccoli seed oil with no superfat needs 12.7 g of 100% NaOH, or 17.8 g of 100% KOH. A 5% superfat uses 5% less.

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In soap

Its main fatty acids in our cited profile are linolenic (20.1%) and linoleic (16.1%). The eight fatty acids used in soap-quality scores make up 58.3% of the profile.

On its own it scores 7 for hardness, 0 for cleansing and 51 for conditioning, with a saturated : unsaturated split of 7 : 51.

High in erucic acid, a long-chain fatty acid, so it needs noticeably less lye than most liquid oils (similar to high-erucic rapeseed or meadowfoam). Erucic content varies between 30% and 50%, so check your COA. Published sources for this oil differ by more than 3%, so checking your supplier's certificate of analysis matters more than usual.

Fatty-acid profile

Fatty acid% of fatty acidsCounts toward
lauric0%hardness, cleansing, bubbly lather
myristic0%hardness, cleansing, bubbly lather
palmitic6.8%hardness, creamy lather
stearic0.2%hardness, creamy lather
ricinoleic0%conditioning, bubbly and creamy lather
oleic15.1%conditioning
linoleic16.1%conditioning
linolenic20.1%conditioning

Basis: Peer-reviewed GC of cold-pressed broccoli seed oil (Front Nutr 2023, Table 1); values as reported (identified acids total 91.3%).

Soap-quality scores (this oil alone)

Hardness7
Cleansing0
Conditioning51
Bubbly lather0
Creamy lather7

Each score adds up certain fatty acids, the way Soap Ledger scores a whole recipe. They are for comparing recipes; they don't predict how a bar will feel, and they say nothing about safety or skin.

Sources

SAP value: 178 mg KOH/g (Theoretical 175-181 from two independent peer-reviewed profiles (33-51% erucic), matching Skinchakra's 175 and Aromantic's mid-point 179. Lotioncrafter's 185-200 is set aside because its own spec sheet's composition implies about 175-180.), from Organic Broccoli Seed Oil product page, Aromantic (UK supplier). Printed value: SAP 168-190 mgKOH/g; erucic 30-50%, oleic 29-40.5%, linoleic <18.5%, linolenic <8%, eicosenoic <11% mg KOH/g.

Published values we checked:

Fatty acids: Potential therapeutic benefits of unconventional oils: assessment of the potential in vitro biological properties of some Rubiaceae, Cucurbitaceae, and Brassicaceae seed oils. Front. Nutr. 10:1171766 (2023), Frontiers. Also checked: Lotioncrafter (US supplier) (Fatty Acid Profile (Area %)).

NaOH and KOH values are converted from mg KOH/g with the molar masses 39.997 and 56.106 and rounded to 6 decimals, exactly as in the Soap Ledger app. Real oils vary by origin, grade and lot: check your supplier's certificate of analysis. Verify every weight before you make this, and follow lye safety. Not a safety or compliance certification.

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