Coconut oil: SAP value and fatty acids

Coconut oil has a saponification value of 256.5 mg KOH/g. One gram needs 0.183 g of sodium hydroxide (NaOH) for bar soap or 0.257 g of potassium hydroxide (KOH) for liquid soap to turn fully into soap, before any superfat.

Key numbers

SAP, NaOH
0.182854 g per g oil
SAP, KOH
0.2565 g per g oil
Saponification value
256.5 mg KOH/g
Iodine value
8.5
INS
248
INCI name
Cocos Nucifera Oil

Example: 100 g of Coconut oil with no superfat needs 18.3 g of 100% NaOH, or 25.6 g of 100% KOH. A 5% superfat uses 5% less.

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In soap

Its main fatty acids in our cited profile are lauric (47.4%) and myristic (18.2%). The eight fatty acids used in soap-quality scores make up 86% of the profile.

On its own it scores 77 for hardness, 66 for cleansing and 9 for conditioning, with a saturated : unsaturated split of 77 : 9.

Fractionated and hydrogenated coconut oils are different ingredients. Published sources for this oil differ by more than 3%, so checking your supplier's certificate of analysis matters more than usual.

Fatty-acid profile

Fatty acid% of fatty acidsCounts toward
lauric47.4%hardness, cleansing, bubbly lather
myristic18.2%hardness, cleansing, bubbly lather
palmitic8.5%hardness, creamy lather
stearic2.9%hardness, creamy lather
ricinoleic0%conditioning, bubbly and creamy lather
oleic7.2%conditioning
linoleic1.7%conditioning
linolenic0.1%conditioning

Basis: Codex CXS 210 Table 1 range midpoints, normalised to 100% (raw midpoints total 103.6%).

Soap-quality scores (this oil alone)

Hardness77
Cleansing66
Conditioning9
Bubbly lather66
Creamy lather11
Iodine9
INS248

Each score adds up certain fatty acids, the way Soap Ledger scores a whole recipe. They are for comparing recipes; they don't predict how a bar will feel, and they say nothing about safety or skin.

Sources

SAP value: 256.5 mg KOH/g (Codex CXS 210 range midpoint), from Codex Alimentarius CXS 210-1999, Standard for Named Vegetable Oils (Table 2: chemical and physical characteristics), FAO/WHO Codex Alimentarius Commission. Printed value: 248–265 mg KOH/g.

Published values we checked:

Fatty acids and iodine: Codex Alimentarius CXS 210-1999, Standard for Named Vegetable Oils (Table 2: chemical and physical characteristics), FAO/WHO Codex Alimentarius Commission. Also checked: U.S. Department of Agriculture, Agricultural Research Service (Fatty acid nutrients (g/100 g food)).

NaOH and KOH values are converted from mg KOH/g with the molar masses 39.997 and 56.106 and rounded to 6 decimals, exactly as in the Soap Ledger app. Real oils vary by origin, grade and lot: check your supplier's certificate of analysis. Verify every weight before you make this, and follow lye safety. Not a safety or compliance certification.

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