Milk thistle seed oil: SAP value and fatty acids

Milk thistle seed oil has a saponification value of 187.84 mg KOH/g. One gram needs 0.134 g of sodium hydroxide (NaOH) for bar soap or 0.188 g of potassium hydroxide (KOH) for liquid soap to turn fully into soap, before any superfat.

Key numbers

SAP, NaOH
0.133908 g per g oil
SAP, KOH
0.18784 g per g oil
Saponification value
187.84 mg KOH/g
Iodine value
103.9
INS
84
INCI name
Silybum Marianum Seed Oil

Example: 100 g of Milk thistle seed oil with no superfat needs 13.4 g of 100% NaOH, or 18.8 g of 100% KOH. A 5% superfat uses 5% less.

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In soap

Its main fatty acids in our cited profile are linoleic (63.2%) and oleic (17.1%). The eight fatty acids used in soap-quality scores make up 94% of the profile.

On its own it scores 13 for hardness, 0 for cleansing and 81 for conditioning, with a saturated : unsaturated split of 13 : 81.

Linoleic-rich oil. The two lab studies differ by ~8%; use the supplier COA. Published sources for this oil differ by more than 3%, so checking your supplier's certificate of analysis matters more than usual.

Fatty-acid profile

Fatty acid% of fatty acidsCounts toward
lauric0%hardness, cleansing, bubbly lather
myristic0.1%hardness, cleansing, bubbly lather
palmitic8.9%hardness, creamy lather
stearic4.3%hardness, creamy lather
ricinoleic0%conditioning, bubbly and creamy lather
oleic17.1%conditioning
linoleic63.2%conditioning
linolenic0.4%conditioning

Basis: Molecules 2023 Table 3, n-hexane-extracted oil, mean of 3 (sums to 100%). The paper's cold-pressed column was not used: it sums to only 93.7% and has large SDs..

Soap-quality scores (this oil alone)

Hardness13
Cleansing0
Conditioning81
Bubbly lather0
Creamy lather13
Iodine104
INS84

Each score adds up certain fatty acids, the way Soap Ledger scores a whole recipe. They are for comparing recipes; they don't predict how a bar will feel, and they say nothing about safety or skin.

Sources

SAP value: 187.84 mg KOH/g (Median of sources' mgKoh_mid), from Characteristics of Silybum marianum as a Potential Source of Dietary Oil and Protein (Ahmad et al., Pakistan Journal of Scientific and Industrial Research 50(1):36–40, 2007), PCSIR (peer-reviewed). Printed value: 194.78 ± 0.23 mg KOH/g.

Published values we checked:

Fatty acids and iodine: Milk Thistle Oil Extracted by Enzyme-Mediated Assisted Solvent Extraction Compared with n-Hexane and Cold-Pressed Extraction (Molecules 2023; DOI 10.3390/molecules28062591), MDPI (peer-reviewed, open access). Also checked: PCSIR (peer-reviewed) (Table 2 (iodine value); abstract and Table 5 (fatty acids)).

NaOH and KOH values are converted from mg KOH/g with the molar masses 39.997 and 56.106 and rounded to 6 decimals, exactly as in the Soap Ledger app. Real oils vary by origin, grade and lot: check your supplier's certificate of analysis. Verify every weight before you make this, and follow lye safety. Not a safety or compliance certification.

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