Neem seed oil: SAP value and fatty acids

Neem seed oil has a saponification value of 195.6 mg KOH/g. One gram needs 0.139 g of sodium hydroxide (NaOH) for bar soap or 0.196 g of potassium hydroxide (KOH) for liquid soap to turn fully into soap, before any superfat.

Key numbers

SAP, NaOH
0.13944 g per g oil
SAP, KOH
0.1956 g per g oil
Saponification value
195.6 mg KOH/g
Iodine value
74.1
INS
122
INCI name
Azadirachta Indica Seed Oil

Example: 100 g of Neem seed oil with no superfat needs 13.9 g of 100% NaOH, or 19.6 g of 100% KOH. A 5% superfat uses 5% less.

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In soap

Its main fatty acids in our cited profile are oleic (51.8%) and linoleic (20.8%). The eight fatty acids used in soap-quality scores make up 100% of the profile.

On its own it scores 27 for hardness, 0 for cleansing and 73 for conditioning, with a saturated : unsaturated split of 27 : 73.

Strong-smelling, bitter oil. Only supplier figures were usable; published lab values vary widely (some well under 150) because of extraction and quality.

Fatty-acid profile

Fatty acid% of fatty acidsCounts toward
lauric0%hardness, cleansing, bubbly lather
myristic0%hardness, cleansing, bubbly lather
palmitic19.6%hardness, creamy lather
stearic7.8%hardness, creamy lather
ricinoleic0%conditioning, bubbly and creamy lather
oleic51.8%conditioning
linoleic20.8%conditioning
linolenic0%conditioning

Basis: AMB Express 2015 Table 1, commercial neem oil bought from local processors in North Cameroon (4 acids only).

Soap-quality scores (this oil alone)

Hardness27
Cleansing0
Conditioning73
Bubbly lather0
Creamy lather27
Iodine74
INS122

Each score adds up certain fatty acids, the way Soap Ledger scores a whole recipe. They are for comparing recipes; they don't predict how a bar will feel, and they say nothing about safety or skin.

Sources

SAP value: 195.6 mg KOH/g (Median of sources' mgKoh_mid), from Chart of Saponification Values for Making Soap (averages compiled 2006 from distributors), Certified Lye. Printed value: NaOH 0.1372 / KOH 0.1932 g alkali per g oil.

Published values we checked:

Fatty acids and iodine: Solvent-free, enzyme-catalyzed biodiesel production from mango, neem, and shea oils via response surface methodology (AMB Express 2015; DOI 10.1186/s13568-015-0172-x), Springer Nature (peer-reviewed, open access). Also checked: MDPI (peer-reviewed, open access) (Table 3, iodine value row); Portland Press (peer-reviewed) (Abstract).

NaOH and KOH values are converted from mg KOH/g with the molar masses 39.997 and 56.106 and rounded to 6 decimals, exactly as in the Soap Ledger app. Real oils vary by origin, grade and lot: check your supplier's certificate of analysis. Verify every weight before you make this, and follow lye safety. Not a safety or compliance certification.

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