Palm olein: SAP value and fatty acids

Palm olein has a saponification value of 198 mg KOH/g. One gram needs 0.141 g of sodium hydroxide (NaOH) for bar soap or 0.198 g of potassium hydroxide (KOH) for liquid soap to turn fully into soap, before any superfat.

Key numbers

SAP, NaOH
0.141151 g per g oil
SAP, KOH
0.198 g per g oil
Saponification value
198 mg KOH/g
Iodine value
58
INS
140
INCI name
Elaeis Guineensis Oil

Example: 100 g of Palm olein with no superfat needs 14.1 g of 100% NaOH, or 19.8 g of 100% KOH. A 5% superfat uses 5% less.

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In soap

Its main fatty acids in our cited profile are oleic (41.9%) and palmitic (39.8%). The eight fatty acids used in soap-quality scores make up 99% of the profile.

On its own it scores 45 for hardness, 1 for cleansing and 54 for conditioning, with a saturated : unsaturated split of 45 : 54.

The liquid fraction of palm oil (more oleic acid). Codex palm superolein is wider, 180–205.

Fatty-acid profile

Fatty acid% of fatty acidsCounts toward
lauric0.3%hardness, cleansing, bubbly lather
myristic1%hardness, cleansing, bubbly lather
palmitic39.8%hardness, creamy lather
stearic4.2%hardness, creamy lather
ricinoleic0%conditioning, bubbly and creamy lather
oleic41.9%conditioning
linoleic11.5%conditioning
linolenic0.3%conditioning

Basis: Codex CXS 210 Table 1 range midpoints (ND = 0; "ND–x" = x/2), normalized to 100% because the raw midpoints sum to 102.3%.

Soap-quality scores (this oil alone)

Hardness45
Cleansing1
Conditioning54
Bubbly lather1
Creamy lather44
Iodine58
INS140

Each score adds up certain fatty acids, the way Soap Ledger scores a whole recipe. They are for comparing recipes; they don't predict how a bar will feel, and they say nothing about safety or skin.

Sources

SAP value: 198 mg KOH/g (Codex CXS 210 range midpoint), from Codex Alimentarius CXS 210-1999, Standard for Named Vegetable Oils (Table 2: chemical and physical characteristics), FAO/WHO Codex Alimentarius Commission. Printed value: 194-202 mg KOH/g.

Published values we checked:

Fatty acids and iodine: Codex Alimentarius CXS 210-1999, Standard for Named Vegetable Oils (Table 2: chemical and physical characteristics), FAO/WHO Codex Alimentarius Commission. Also checked: Food Safety and Standards Authority of India (FSSAI) (2.2.1 item 20 Palmolein (iodine value); FA table reproduces Codex ranges).

NaOH and KOH values are converted from mg KOH/g with the molar masses 39.997 and 56.106 and rounded to 6 decimals, exactly as in the Soap Ledger app. Real oils vary by origin, grade and lot: check your supplier's certificate of analysis. Verify every weight before you make this, and follow lye safety. Not a safety or compliance certification.

Last updated .